Fabrication of Graphene-Encapsulated Oxide Nanoparticles: Towards High-Performance Anode Materials for Lithium Storage

被引:938
作者
Yang, Shubin [1 ]
Feng, Xinliang [1 ]
Ivanovici, Sorin [2 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] BASF SE, GVC FJ550, D-67056 Ludwigshafen, Germany
关键词
cobalt oxides; electrochemistry; graphene; nanoparticles; silica; HOLLOW CARBON SPHERES; LI-ION BATTERIES; TIN-NANOPARTICLES; ELECTRODES; NANOSHEETS; CO3O4; COMPOSITES; GAS;
D O I
10.1002/anie.201003485
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Storage shells: The assembly of negatively charged graphene oxide and positively charged oxide nanoparticles by electrostatic interactions, and subsequent chemical reduction, leads to metal oxides encapsulated in flexible and ultrathin graphene shells (see picture). These electrochemically active nanoparticles show a remarkable lithium storage capacity, with an excellent cycle performance. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:8408 / 8411
页数:4
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