Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

被引：160

作者：

Gallego, Almudena ^{[1
]}

Hermosa, Cristina ^{[1
]}

Castillo, Oscar ^{[2
]}

Berlanga, Isadora ^{[1
]}

Gomez-Garcia, Carlos J. ^{[3
]}

Mateo-Marti, Eva ^{[4
]}

Martinez, Jose I. ^{[5
]}

Flores, Fernando ^{[5
]}

Gomez-Navarro, Cristina ^{[6
]}

Gomez-Herrero, Julio ^{[6
]}

Delgado, Salome ^{[1
]}

Zamora, Felix ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Inorgan, E-28049 Madrid, Spain

[2] Univ Pais Vasco UPV EHU, Dept Quim Inorgan, E-48080 Bilbao, Spain

[3] Univ Valencia, Inst Ciencia Mol, E-46980 Valencia, Spain

[4] Ctr Astrobiol CSIC INTA, Madrid 28850, Spain

[5] Univ Autonoma Madrid, Dept Fis Teor Mat Condensada, E-28049 Madrid, Spain

[6] Univ Autonoma Madrid, Dept Fis Mat Condensada, E-28049 Madrid, Spain

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 15期

关键词：

coordination polymers; 2D materials; multifunctional materials; MOFs; MOF on surfaces; crystal-to-crystal transformation; COVALENT ORGANIC FRAMEWORKS; FACILE SYNTHESIS; CRYSTALLINE; LUMINESCENT; NANOSTRUCTURES; NANOSHEETS; GRAPHENE;

D O I：

10.1002/adma.201204676

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2141 / 2146

页数：6

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