Synthesis of Free-Standing, Monolayered Organometallic Sheets at the Air/Water Interface

被引：240

作者：

Bauer, Thomas ^{[1
]}

Zheng, Zhikun ^{[1
]}

Renn, Alois ^{[2
]}

Enning, Raoul ^{[3
]}

Stemmer, Andreas ^{[3
]}

Sakamoto, Junji ^{[1
]}

Schlueter, A. Dieter ^{[1
]}

机构：

[1] ETH, Dept Mat, Inst Polymers, Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland

[2] ETH, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland

[3] ETH, Nanotechnol Grp, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 34期

基金：

瑞士国家科学基金会;

关键词：

coordination chemistry; dynamic bond formation; Langmuir-Blodgett films; polymerization; terpyridine; COORDINATION POLYMERS; BUILDING-BLOCKS; METAL-COMPLEXES; SURFACE; ARCHITECTURES; CHAINS; UNITS; 2D; NANOSTRUCTURES; RUTHENIUM(II);

D O I：

10.1002/anie.201100669

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sheets and rational synthesis are not like fire and water! Hexafunctional terpyridine monomers can be laterally connected by metal salts to result in a mechanically stable, sheetlike entity that can be transferred from the air/water interface to a solid substrate (see the folded, ca. 1.4 nm thin film) and spanned over micrometer-sized holes. This result is considered an important step on the way to 2D polymers. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7879 / 7884

页数：6

共 65 条

[1] Single Layer of Polymeric Fe-Phthalocyanine: An Organometallic Sheet on Metal and Thin Insulating Film [J].

Abel, Mathieu ;

Clair, Sylvain ;

Ourdjini, Oualid ;

Mossoyan, Mireille ;

Porte, Louis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1203-1205

[2] Single layers of a multifunctional laminar Cu(I,II) coordination polymer [J].

Amo-Ochoa, Pilar ;

Welte, Lorena ;

Gonzalez-Prieto, Rodrigo ;

Sanz Miguel, Pablo J. ;

Gomez-Garcia, Carlos J. ;

Mateo-Marti, Eva ;

Delgado, Salome ;

Gomez-Herrero, Julio ;

Zamora, Felix .

CHEMICAL COMMUNICATIONS, 2010, 46 (19) :3262-3264

[3] New functional polymers and materials based on 2,2′:6′,2"-terpyridine metal complexes [J].

Andres, PR ;

Schubert, US .

ADVANCED MATERIALS, 2004, 16 (13) :1043-1068

[4]

[Anonymous], 2009, ANGEW CHEM INT EDIT

[5]

[Anonymous], ANGEW CHEM

[6] TEMPLATE SYNTHESIS OF 2-DIMENSIONAL NETWORK OF CROSS-LINKED ACRYLATE POLYMER IN A CAST MULTIBILAYER FILM [J].

ASAKUMA, S ;

OKADA, H ;

KUNITAKE, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) :1749-1755

[7] Luminescent and redox-active polynuclear transition metal complexes [J].

Balzani, V ;

Juris, A ;

Venturi, M ;

Campagna, S ;

Serroni, S .

CHEMICAL REVIEWS, 1996, 96 (02) :759-833

[8] Self-assembly, structure, and dynamic interconversion of metallosupramolecular architectures generated by Pb(II) binding-induced unfolding of a helical ligand [J].

Barboiu, M ;

Vaughan, G ;

Graff, R ;

Lehn, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10257-10265

[9] Supramolecular architectures and nanostructures at metal surfaces [J].

Barth, JV ;

Weckesser, J ;

Lin, N ;

Dmitriev, A ;

Kern, K .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2003, 76 (05) :645-652

[10] Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2′:6′,2"-Terpyridin-4′-yl Units at the Periphery [J].

Bauer, Thomas ;

Schlueter, A. Dieter ;

Sakamoto, Junji .

SYNLETT, 2010, (06) :877-880

← 1 2 3 4 5 6 7 →