Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2′:6′,2"-Terpyridin-4′-yl Units at the Periphery

被引：27

作者：

Bauer, Thomas ^{[1
]}

Schlueter, A. Dieter ^{[1
]}

Sakamoto, Junji ^{[1
]}

机构：

[1] ETH, Inst Polymers, Polymer Chem Lab, Dept Mat, CH-8093 Zurich, Switzerland

来源：

SYNLETT | 2010年 / 06期

关键词：

palladium; steric hindrance; chelates; supramolecular chemistry; periodic network; CROSS-COUPLING REACTION; STRATEGIES; COMPLEXES; DESIGN; METAL;

D O I：

10.1055/s-0029-1219541

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A set of shape-persistent star- shaped monomers which are multiply equipped with 2,2':6',2 ''-terpyridin-4'-yl units has been synthesized. The synthetic sequences rest upon the Suzuki-Miyaura cross-coupling reaction which includes a sterically challenging sixfold coupling of a bulky aryl boronate to hexabromobenzene.

引用

页码：877 / 880

页数：4

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