Synthesis of Free-Standing, Monolayered Organometallic Sheets at the Air/Water Interface

被引：240

作者：

Bauer, Thomas ^{[1
]}

Zheng, Zhikun ^{[1
]}

Renn, Alois ^{[2
]}

Enning, Raoul ^{[3
]}

Stemmer, Andreas ^{[3
]}

Sakamoto, Junji ^{[1
]}

Schlueter, A. Dieter ^{[1
]}

机构：

[1] ETH, Dept Mat, Inst Polymers, Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland

[2] ETH, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland

[3] ETH, Nanotechnol Grp, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 34期

基金：

瑞士国家科学基金会;

关键词：

coordination chemistry; dynamic bond formation; Langmuir-Blodgett films; polymerization; terpyridine; COORDINATION POLYMERS; BUILDING-BLOCKS; METAL-COMPLEXES; SURFACE; ARCHITECTURES; CHAINS; UNITS; 2D; NANOSTRUCTURES; RUTHENIUM(II);

D O I：

10.1002/anie.201100669

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sheets and rational synthesis are not like fire and water! Hexafunctional terpyridine monomers can be laterally connected by metal salts to result in a mechanically stable, sheetlike entity that can be transferred from the air/water interface to a solid substrate (see the folded, ca. 1.4 nm thin film) and spanned over micrometer-sized holes. This result is considered an important step on the way to 2D polymers. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7879 / 7884

页数：6

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