Water-soluble neutral calix[4]arene-lanthanide complexes: Synthesis and luminescence properties

被引：64

作者：

Steemers, FJ

Meuris, HG

Verboom, W

Reinhoudt, DN

vanderTol, EB

Verhoeven, JW

机构：

[1] UNIV TWENTE,LAB SUPRAMOL CHEM & TECHNOL,NL-7500 AE ENSCHEDE,NETHERLANDS

[2] UNIV AMSTERDAM,ORGAN CHEM LAB,NL-1018 WS AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1997年 / 62卷 / 13期

关键词：

D O I：

10.1021/jo970132j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Water-soluble calix[4]arenes 10a,b with chromophores (''antenna'') attached to the lower rim via a short spacer are described. In the neutral lanthanide complexes of 10a,b photoexcitation of the antenna induces lanthanide emission via intramolecular energy transfer. Calix[4]arene 10b with a chrysene moiety as sensitizer shows strong lanthanide emission for Eu3+ with an excitation maximum at lambda = 363 nm.

引用

页码：4229 / 4235

页数：7

共 45 条

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