Nonsolvent applications of ionic liquids in biotransformations and organocatalysis

被引：207

作者：

de Maria, Pablo Dominguez ^{[1
]}

机构：

[1] Chem Proc & Product Technol Dept, NL-6800 SB Arnhem, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 37期

关键词：

biocatalysis; biotransformations; enzyme catalysis; ionic liquids; organocatalysis;

D O I：

10.1002/anie.200703305

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

The application of room-temperature ionic liquids (RTILs)as (co)solvents and/or reagents is well documented. However, RTILS also have nonsolvent applications in biotransformations and organocatalysis. Examples are the anchoring of substrates to RTILs; ionic-liquid-coated enzymes (ILCE) and enzyme-IL colyophilization; the construction of biocatalytic ternary reaction systems; the combination of enzymes, RTILs, membranes, and (bio)electrochemistry; and ionic-liquid-supported organocatalysts. These strategies provide more robust, more efficient, and more enantioselective bio- and organo-catalysts with many practical applications. As shown herein, RTILs offer a wide range of promising alternatives to conventional chemistry. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6960 / 6968

页数：9

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