Phosphorylation of p-tert-butylthiocalix[4]arene:: Reaction with phosphorus trichloride.

被引：16

作者：

Antipin, IS

Stoikov, II

Gubaidullin, AT

Litvinov, IA

Weber, D

Habicher, WD

Konovalov, AI

机构：

[1] Kazan VI Lenin State Univ, Kazan 420008, Russia

[2] AE Arbuzov Inst Organ & Phys Chem, Kazan 420083, Russia

[3] Tech Univ Dresden, D-01062 Dresden, Germany

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 48期

关键词：

D O I：

10.1016/S0040-4039(99)01774-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of the first phosphorylated derivatives of p-tert-butylthiocalix[4]arene was achieved by reaction with phosphorus trichloride. The product containing two cyclic P(III) atoms is not hydrolytically stable. The flattened 1,2-alternate conformation of a P(IV) derivative was established by H-1, C-13, P-31 NMR experiments and X-ray analysis. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：8461 / 8464

页数：4

共 16 条

[1] Thiacalixarenes:: Synthesis and structural analysis of thiacalix[4]arene and of p-tert-butylthiacalix[4]arene [J].