The Chemistry and Applications of Metal-Organic Frameworks

被引：13229

作者：

Furukawa, Hiroyasu ^{[1
,2
]}

Cordova, Kyle E. ^{[1
,2
]}

O'Keeffe, Michael ^{[3
,4
,5
]}

Yaghi, Omar M. ^{[1
,2
,4
,5
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA

[3] Arizona State Univ, Dept Chem, Tempe, AZ 87240 USA

[4] NanoCentury KAIST Inst, Taejon 305701, South Korea

[5] World Class Univ, Grad Sch Energy Environm Water & Sustainabil, Taejon 305701, South Korea

来源：

SCIENCE | 2013年 / 341卷 / 6149期

关键词：

COORDINATION POLYMER CRYSTALS; HIGH H-2 ADSORPTION; CARBON-DIOXIDE; SURFACE-AREAS; HYDROGEN ADSORPTION; CATALYTIC-ACTIVITY; PROTON CONDUCTION; HIGH-CAPACITY; THIN-FILMS; STORAGE;

D O I：

10.1126/science.1230444

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.

引用

页码：974 / +

页数：13

共 133 条

[1] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate) [J].