Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids

被引：102

作者：

Nishimura, T ^{[1
]}

Hirabayashi, S ^{[1
]}

Yasuhara, Y ^{[1
]}

Hayashi, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 08期

关键词：

D O I：

10.1021/ja058763f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids proceeded in high yields with high regio- and enantioselectivity to give chiral allylphosphine oxides of up to 98% ee. The structural determination of the key intermediate, a π-allylrhodium complex, was successful to establish the catalytic cycle of the reaction. Copyright © 2006 American Chemical Society.

引用

页码：2556 / 2557

页数：2

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