Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds

被引：1009

作者：

Fagnou, K

Lautens, M

机构：

[1] Univ Toronto, Dept Chem, Davenport Res Labs, Toronto, ON M5S 3H6, Canada

[2] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 01期

关键词：

D O I：

10.1021/cr020007u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The carbon-carbon bond forming reactions of organometallic compounds catalyzed by rhodium were studied. The crystal structures of rhodium-aryl complexes were also obtained with a diverse range of ancillary ligands. It was found that the demetalations were catalyzed by the rhodium metal and occured because the aryl-rhodium bond could be more sensitive to protonolysis than the original organometallic compound from which it was derived.

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页码：169 / 196

页数：28

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