Silyl functionalization of polyolefins

被引：33

作者：

Chauhan, BPS

Balagam, B

机构：

[1] CUNY Coll Staten Isl, Dept Chem, CePM, Nanomat Lab, Staten Isl, NY 10314 USA

[2] CUNY Coll Staten Isl, Grad Ctr, Staten Isl, NY 10314 USA

来源：

MACROMOLECULES | 2006年 / 39卷 / 06期

关键词：

D O I：

10.1021/ma052508y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The strategy to generate new materials with enhanced or specific physical and chemical properties by synthetic modification of polymers was described. The new strategies for the generation of catalytically active metal nanoclusters and their utility as potent recyclable catalysts for various transformations. Gel permeation chromatography (GPC) was used to determine the molecular weight and chain length properties of functionalized polymers. The solvent tetrahydrofuran (THF) was found to show only 50% hydrosilylation even after long reaction periods.

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页码：2010 / 2012

页数：3

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