A facile one-pot synthesis of ruthenium hydroxide nanoparticles on magnetic silica: aqueous hydration of nitriles to amides

被引：121

作者：

Baig, R. B. Nasir ^{[1
]}

Varma, Rajender S. ^{[1
]}

机构：

[1] US Environm Protect Agcy, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 50期

关键词：

CATALYZED HYDRATION; HETEROGENEOUS CATALYST; EFFICIENT HYDRATION; HYDROLYSIS; CHEMISTRY; MICROWAVE; OXIDATION; WATER; TRANSFORMATION; HYDROGENATION;

D O I：

10.1039/c2cc32566g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-pot synthesis of ruthenium hydroxide nanoparticles on magnetic silica is described which involves the in situ generation of magnetic silica (Fe3O4@SiO2) and ruthenium hydroxide immobilization; the hydration of nitriles occurs in high yield and excellent selectivity using this catalyst which proceeds exclusively in aqueous medium under neutral conditions.

引用

页码：6220 / 6222

页数：3