Linking of metal centres through boryl ligands: synthesis, spectroscopic and structural characterisation of symmetrically bridged boryl complexes

被引:22
作者
Aldridge, S
Calder, RJ
Rossin, A
Dickinson, AA
Willock, DJ
Jones, C
Evans, DJ
Steed, JW
Light, EM
Coles, SJ
Hursthouse, MB
机构
[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales
[2] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England
[3] Kings Coll London, Dept Chem, London WC2R 2LS, England
[4] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 09期
关键词
D O I
10.1039/b200695m
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dinuclear species containing iron centres linked via various bridging boryl ligands have been synthesised and a combination of crystallographic, computational and spectroscopic (Mossbauer, IR, Raman) techniques have been used to probe the bonding in these complexes.
引用
收藏
页码:2020 / 2026
页数:7
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共 61 条
  • [21] Phosphine exchange reactions involving cis-[Pt(PPh3)2(Bcat)2] (cat=1,2-O2C6H4) and the oxidative addition of 1,2-B2Cl2(NMe2)2 to Pt0
    Curtis, D
    Lesley, MJG
    Norman, NC
    Orpen, AG
    Starbuck, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (10): : 1687 - 1694
  • [22] Synthesis and characterization of rhodium(I) boryl and rhodium(III) tris(boryl) compounds: Molecular structures of [(PMe(3))(4)Rh(B(cat))] and fac-[(PMe(3))(3)Rh(B(cat))(3)] (cat equals 1,2-O2C6H4)
    Dai, CY
    Stringer, G
    Marder, TB
    Scott, AJ
    Clegg, W
    Norman, NC
    [J]. INORGANIC CHEMISTRY, 1997, 36 (03) : 272 - &
  • [23] Analysis of bonding in cyclopentadienyl transition-metal boryl complexes
    Dickinson, AA
    Willock, DJ
    Calder, RJ
    Aldridge, S
    [J]. ORGANOMETALLICS, 2002, 21 (06) : 1146 - 1157
  • [24] AN AB-INITIO INVESTIGATION OF THE RH-I-CATALYZED HYDROBORATION OF C=C BONDS - EVIDENCE FOR HYDROGEN MIGRATION IN THE KEY STEP
    DORIGO, AE
    SCHLEYER, PV
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (01): : 115 - 118
  • [25] Structure and bonding of transition metal-boryl compounds.: Theoretical study of [(PH3)2(CO)ClOs-BR2] and [(PH3)2(CO)2ClOs-BR2] (BR2 = BH2, BF2, B(OH)2, B(OCH=CHO), Bcat)
    Giju, KT
    Bickelhaupt, FM
    Frenking, G
    [J]. INORGANIC CHEMISTRY, 2000, 39 (21) : 4776 - 4785
  • [26] Small heteroborane cluster systems .6. Mossbauer effect study of iron substituted small metallaborane clusters
    Goodreau, BH
    Orlando, LR
    Long, GJ
    Spencer, JT
    [J]. INORGANIC CHEMISTRY, 1996, 35 (22) : 6579 - 6585
  • [27] TRANSITION-METAL BORYL COMPLEXES - STRUCTURE AND REACTIVITY OF CPFE(CO)2BCAT AND CPFE(CO)2BPH2
    HARTWIG, JF
    HUBER, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (11) : 4908 - 4909
  • [28] Boryls bound to iron carbonyl. Structure of a rare bis(boryl) complex, synthesis of the first anionic boryl, and reaction chemistry that includes the synthetic equivalent of boryl anion transfer
    He, XM
    Hartwig, JF
    [J]. ORGANOMETALLICS, 1996, 15 (01) : 400 - 407
  • [29] Transition metal-boryl compounds: Synthesis, reactivity, and structure
    Irvine, GJ
    Lesley, MJG
    Marder, TB
    Norman, NC
    Rice, CR
    Robins, EG
    Roper, WR
    Whittell, GR
    Wright, LJ
    [J]. CHEMICAL REVIEWS, 1998, 98 (08) : 2685 - 2722
  • [30] Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate
    Ishiyama, T
    Takagi, J
    Ishida, K
    Miyaura, N
    Anastasi, NR
    Hartwig, JF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (03) : 390 - 391