Intercalation of 2,2′-bipyrtdyl, 2,4′-bipyridyl and 4,4′-bipyridyl into γ-zirconium phosphate.: Physical-chemical characterization and solvent effect on the intercalation

被引：12

作者：

Ferragina, C

Cafarelli, P

De Stefanis, A

Mattei, G

机构：

[1] CNR, IMAI, I-00016 Monterotondo, Italy

[2] CNR, ICMAT, I-00016 Monterotondo, Italy

来源：

MATERIALS RESEARCH BULLETIN | 1999年 / 34卷 / 07期

关键词：

layered compounds; nanostructures; intercalation reactions;

D O I：

10.1016/S0025-5408(99)00105-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The uptake into gamma-zirconium phosphate by batch method of 2,2'-bipyridyl, 2,4'-bipyridyl, and 4,4'-bipyridyl in ethanol:water solutions of various solvent ratios has been studied. The obtained materials were examined by powder X-ray diffraction (PXRD), thermogravimetric and differential thermal analysis (TG-DTA) techniques, and UV-vis, IR and Raman spectroscopy. It has been found that the ligand content into the exchanger depends on batch temperature, ligand:exchanger ratio in the contact batch, ethanol:water solvent ratio, and isomeric nitrogen position in the diamines. The highest uptake was obtained for the ligand 2,2'-bipyridyl with an ethanol:water ratio of 1:9. (C) 1999 Elsevier Science Ltd.

引用

页码：1039 / 1053

页数：15

共 24 条

[11] PILLAR CHEMISTRY .5. INTERCALATION OF 2,2'-BIPYRIDINE, 1,10-PHENANTHROLINE, AND 2,9-DIMETHYL-1,10-PHENANTHROLINE INTO GAMMA-ZIRCONIUM PHOSPHATE AND FORMATION OF INTERLAYER COPPER(II) COMPLEXES [J].