A bimetallic molybdenum(VI) and stannum(IV) catalyst for the transesterification of dimethyl oxalate with phenol

The transesterification of dimethyl oxalate (DMO) with phenol to methyl phenyl oxalate (MPO) and diphenyl oxalate (DPO) was carried out in liquid phase under facile catalytic conditions. A series of bimetallic, MoO3-SnO2/SiO2, catalysts with various Mo and Sri content were prepared by sequential impregnation of cationic Mo species and cationic Sn complexes using impregnation method. The effects of mass ratio of Mo:Sn, amount of Sri additive, and Mo(Sn) laoding amount on activities of transesterification of dimethyl oxalate with phenol were investigated. The evaluation results showed that MoO3-SnO2/SiO2 catalyst with 14 wt% Mo(Sn) content performed best, giving 74.6% DMO conversion and 99.5% selectivity to MPO and DPO. This new heterogeneous catalyst provided not only an excellent selectivity (99% to MPO and DPO) and high yield of MPO and DPO but also a simple and practical protocol for DPC synthesis. (C) 2004 Elsevier B.V. All rights reserved.