Synthesis of novel organoboron polymers by haloboration polymerization of bisallene compounds and their reactions

被引：13

作者：

Matsumi, N ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DEPT POLYMER CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

POLYMER BULLETIN | 1997年 / 39卷 / 03期

关键词：

HYDROBORATION POLYMERIZATION;

D O I：

10.1007/s002890050151

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Novel organoboron polymers were prepared by haloboration polymerizatrion of bisallene compounds. The polymers obtained have allylborane halide units in their main chain and can be expected as a novel type of reactive polymers. For example, the polymer prepared by haloboration polymerization between tribromoborane (1) and 1,2,10,11-dodecatetraene (2b) was subjected to chain transformation reaction (dichloromethyl methyl ether rearrangement) to give the corresponding polyalcohol or polyketone. Haloboration-phenylboration polymerization of aliphatic bisallenes by using diphenylbromoborane also gave the corresponding polymers.

引用

页码：295 / 302

页数：8

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