Vapor-Phase Metalation by Atomic Layer Deposition in a Metal-Organic Framework

被引：838

作者：

Mondloch, Joseph E. ^{[1
]}

Bury, Wojciech ^{[1
,2
]}

Fairen-Jimenez, David ^{[1
]}

Kwon, Stephanie ^{[1
]}

DeMarco, Erica J. ^{[1
]}

Weston, Mitchell H. ^{[1
]}

Sarjeant, Amy A. ^{[1
]}

Nguyen, SonBinh T. ^{[1
]}

Stair, Peter C. ^{[1
]}

Snurr, Randall Q. ^{[1
]}

Farha, Omar K. ^{[1
]}

Hupp, Joseph T. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem & Chem & Biol Engn, Evanston, IL 60208 USA

[2] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 28期

关键词：

D O I：

10.1021/ja4050828

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) have received attention for a myriad of potential applications including catalysis, gas storage, and gas separation. Coordinatively unsaturated metal ions often enable key functional behavior of these materials. Most commonly, MOFs have been metalated from the condensed phase (i.e., from solution). Here we introduce a new synthetic strategy capable of metallating MOFs from the gas phase: atomic layer deposition (ALD). Key to enabling metalation by AID In MOFs (AIM) was the synthesis of NU-1000, a new, thermally stable, Zr-based MOP with spatially oriented -OH groups and large 1D mesopores and apertures.

引用

页码：10294 / 10297

页数：4

共 28 条

[11] Atomic Layer Deposition: An Overview [J].

George, Steven M. .

CHEMICAL REVIEWS, 2010, 110 (01) :111-131

[12] A kinetic model for step coverage by atomic layer deposition in narrow holes or trenches [J].

Gordon, RG ;

Hausmann, D ;

Kim, E ;

Shepard, J .

CHEMICAL VAPOR DEPOSITION, 2003, 9 (02) :73-78

[13] Aerogel templated ZnO dye-sensitized solar cells [J].

Hamann, Thomas W. ;

Martinson, Alex B. E. ;

Elam, Jeffrey W. ;

Pellin, Michael J. ;

Hupp, Joseph T. .

ADVANCED MATERIALS, 2008, 20 (08) :1560-+

[14] INFRARED STUDIES OF THE ADSORPTION OF SYNTHESIS GAS ON ZIRCONIUM DIOXIDE [J].

HE, MY ;

EKERDT, JG .

JOURNAL OF CATALYSIS, 1984, 87 (02) :381-388

[15]

Horike S, 2009, NAT CHEM, V1, P695, DOI [10.1038/nchem.444, 10.1038/NCHEM.444]

[16] Titration of Zr3(μ-OH) Hydroxy Groups at the Cornerstones of Bulk MOF UiO-67, [Zr6O4(OH)4(biphenyldicarboxylate)6], and Their Reaction with [AuMe(PMe3)] [J].

Larabi, Cherif ;

Quadrelli, Elsje Alessandra .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (18) :3014-3022

[17] Metal-organic framework materials as catalysts [J].

Lee, JeongYong ;

Farha, Omar K. ;

Roberts, John ;

Scheidt, Karl A. ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1450-1459

[18] Robust, Functional Nanocrystal Solids by Infilling with Atomic Layer Deposition [J].

Liu, Yao ;

Gibbs, Markelle ;

Perkins, Craig L. ;

Tolentino, Jason ;

Zarghami, Mohammad H. ;

Bustamante, Jorge, Jr. ;

Law, Matt .

NANO LETTERS, 2011, 11 (12) :5349-5355

[19] Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition [J].

Lu, Junling ;

Fu, Baosong ;

Kung, Mayfair C. ;

Xiao, Guomin ;

Elam, Jeffrey W. ;

Kung, Harold H. ;

Stair, Peter C. .

SCIENCE, 2012, 335 (6073) :1205-1208

[20] Atomic Layer Deposition of Nanostructured Materials for Energy and Environmental Applications [J].

Marichy, Catherine ;

Bechelany, Mikhael ;

Pinna, Nicola .

ADVANCED MATERIALS, 2012, 24 (08) :1017-1032

← 1 2 3 →