Design, preparation and application of conjugated microporous polymers

被引：103

作者：

Liu, Qingquan ^{[1
]}

Tang, Zhe ^{[1
]}

Wu, Minda ^{[1
]}

Zhou, Zhihua ^{[1
]}

机构：

[1] Hunan Univ Sci & Technol, Minist Educ, Sch Chem & Chem Engn, Key Lab Theoret Chem & Mol Simulat, Xiangtan 411201, Peoples R China

来源：

POLYMER INTERNATIONAL | 2014年 / 63卷 / 03期

基金：

中国国家自然科学基金;

关键词：

conjugated microporous polymers; specific surface area; Sonogashira-Hagihara; Yamamoto coupling; HIGH-SURFACE-AREA; COVALENT-ORGANIC FRAMEWORKS; CROSS-COUPLING REACTIONS; HYDROGEN STORAGE; INTRINSIC MICROPOROSITY; DISUBSTITUTED POLYACETYLENES; CO2; CAPTURE; HYPERCROSSLINKED POLYSTYRENE; ELECTRICAL-CONDUCTIVITY; HETEROGENEOUS CATALYSIS;

D O I：

10.1002/pi.4640

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Conjugated microporous polymers (CMPs) are of great interest because these types of materials have high specific surface area and pore diameters less than 2 nm. CMPs have found applications in the fields of hydrogen storage, heterogeneous catalysts, gas-permeable membranes and light-emitting organics. A large number of recent reports have demonstrated that CMPs can be prepared using several approaches like noble metal-mediated ethynyl, Sonogashira-Hagihara coupling, Suzuki coupling and Yamamoto coupling reactions. In this review, the synthetic routes, functionalization and potential applications of CMPs are systematically introduced. (c) 2013 Society of Chemical Industry

引用

页码：381 / 392

页数：12

共 310 条

[1] Mechanism of the palladium-catalyzed homocoupling of arylboronic acids: Key involvement of a palladium peroxo complex [J].