Design, preparation and application of conjugated microporous polymers

被引:103
作者
Liu, Qingquan [1 ]
Tang, Zhe [1 ]
Wu, Minda [1 ]
Zhou, Zhihua [1 ]
机构
[1] Hunan Univ Sci & Technol, Minist Educ, Sch Chem & Chem Engn, Key Lab Theoret Chem & Mol Simulat, Xiangtan 411201, Peoples R China
基金
中国国家自然科学基金;
关键词
conjugated microporous polymers; specific surface area; Sonogashira-Hagihara; Yamamoto coupling; HIGH-SURFACE-AREA; COVALENT-ORGANIC FRAMEWORKS; CROSS-COUPLING REACTIONS; HYDROGEN STORAGE; INTRINSIC MICROPOROSITY; DISUBSTITUTED POLYACETYLENES; CO2; CAPTURE; HYPERCROSSLINKED POLYSTYRENE; ELECTRICAL-CONDUCTIVITY; HETEROGENEOUS CATALYSIS;
D O I
10.1002/pi.4640
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Conjugated microporous polymers (CMPs) are of great interest because these types of materials have high specific surface area and pore diameters less than 2 nm. CMPs have found applications in the fields of hydrogen storage, heterogeneous catalysts, gas-permeable membranes and light-emitting organics. A large number of recent reports have demonstrated that CMPs can be prepared using several approaches like noble metal-mediated ethynyl, Sonogashira-Hagihara coupling, Suzuki coupling and Yamamoto coupling reactions. In this review, the synthetic routes, functionalization and potential applications of CMPs are systematically introduced. (c) 2013 Society of Chemical Industry
引用
收藏
页码:381 / 392
页数:12
相关论文
共 310 条
[61]   Advancesn in CO2 capture technology -: The US Department of Energy's Carbon Sequestration Program [J].
Figueroa, Jose D. ;
Fout, Timothy ;
Plasynski, Sean ;
McIlvried, Howard ;
Srivastava, Rameshwar D. .
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2008, 2 (01) :9-20
[62]   Adsorption of gases, vapors and liquids by microporous adsorbents [J].
Fomkin, AA .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2005, 11 (3-4) :425-436
[63]  
Forster M, 2000, MACROMOL RAPID COMM, V21, P810, DOI 10.1002/1521-3927(20000801)21:12<810::AID-MARC810>3.0.CO
[64]  
2-D
[65]   Optimisation of Permanganate Oxidation and Suzuki-Miyaura Coupling Steps in the Synthesis of a Nav1.8 Sodium Channel Modulator [J].
Fray, M. Jonathan ;
Gillmore, Adam T. ;
Glossop, Melanie S. ;
McManus, David J. ;
Moses, Ian B. ;
Praquin, Celine F. B. ;
Keeves, Keith A. ;
Thompson, Lisa R. .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2010, 14 (01) :263-271
[66]  
Friedel C., 1877, B SOC CHIM FR, V27, P530
[67]   Electroluminescence in conjugated polymers [J].
Friend, RH ;
Gymer, RW ;
Holmes, AB ;
Burroughes, JH ;
Marks, RN ;
Taliani, C ;
Bradley, DDC ;
Dos Santos, DA ;
Brédas, JL ;
Lögdlund, M ;
Salaneck, WR .
NATURE, 1999, 397 (6715) :121-128
[68]   An Ab Initio Force Field for Predicting Hydrogen Storage in IRMOF Materials [J].
Fu, Jia ;
Sun, Huai .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (52) :21815-21824
[69]   Ultrahigh Porosity in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Ko, Nakeun ;
Go, Yong Bok ;
Aratani, Naoki ;
Choi, Sang Beom ;
Choi, Eunwoo ;
Yazaydin, A. Oezguer ;
Snurr, Randall Q. ;
O'Keeffe, Michael ;
Kim, Jaheon ;
Yaghi, Omar M. .
SCIENCE, 2010, 329 (5990) :424-428
[70]   Preparation of Size-Selective Nanoporous Polymer Networks of Aromatic Rings: Potential Adsorbents for Hydrogen Storage [J].
Germain, Jonathan ;
Svec, Frantisek ;
Frechet, Jean M. J. .
CHEMISTRY OF MATERIALS, 2008, 20 (22) :7069-7076