Synthesis of aromatic nitriles via the temporary complexation of nitroarenes to the cationic cyclopentadienyliron moiety

被引：1

作者：

Abd-El-Aziz, AS ^{[1
]}

Boraie, W ^{[1
]}

Gavel, NT ^{[1
]}

机构：

[1] Univ Winnipeg, Dept Chem, Winnipeg, MB R3B 2E9, Canada

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 08期

关键词：

D O I：

10.1021/om981022l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyanide addition to cyclopentadienyliron complexes of substituted nitroarenes produced nitrile adducts where the cyano group added in the ortho position with respect to the nitro group. Cleavage of the cyclopentadienyliron moiety via oxidative demetalation with DDQ led to the isolation of functionalized aromatic nitriles in good yields.

引用

页码：1562 / 1564

页数：3

共 33 条

[11]

JAOUEN G, 1970, J ORGANOMET CHEM, V21, P43

[12] EFFICIENT ENZYMATIC CYCLIZATION OF 2-(CARBAMOYLOXY)-BENZONITRILE AND 2-(SULFAMOYLOXY)-BENZONITRILE BY ULTRASONICALLY STIMULATED BAKERS-YEAST [J].

KAMAL, A ;

RAO, MV ;

RAO, AB .

HETEROCYCLES, 1990, 31 (04) :577-579

[13]

KAYUSHINA EN, 1986, IZV AKAD NAUK K, V1, P1625

[14]

KUNDIG EP, 1989, J AM CHEM SOC, V111, P1804

[15] RECENT ADVANCES IN ARENE TRANSFORMATION REACTIONS VIA CHROMIUM COMPLEXES [J].

KUNDIG, EP .

PURE AND APPLIED CHEMISTRY, 1985, 57 (12) :1855-1864

[16] THE MECHANISM OF HYDROGEN MIGRATION IN CYCLOHEXADIENYLMANGANESE TRICARBONYL [J].

LAMANNA, W ;

BROOKHART, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (10) :3490-3494

[17] THE REACTION OF CHIRAL NUCLEOPHILES WITH ORGANOMANGANESE ARENE COMPLEXES [J].

MILES, WH ;

SMILEY, PM ;

BRINKMAN, HR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (24) :1897-1899

[18] A FORMAL SYNTHESIS OF (+)-JUVABIONE [J].

MILES, WH ;

BRINKMAN, HR .

TETRAHEDRON LETTERS, 1992, 33 (05) :589-592

[19] LIGAND-EXCHANGE AND HYDROGEN SHIFT REACTIONS IN "CYCLOHEXADIENYLTRICARBONYLMANGANESE SERIES [J].

MUNRO, GAM ;

PAUSON, PL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (04) :134-135

[20]

Pearson A.J., 1994, IRON COMPOUNDS ORGAN

← 1 2 3 4 →