Hydride encapsulation in s-block metal inverse crown chemistry

被引：88

作者：

Gallagher, DJ ^{[1
]}

Henderson, KW ^{[1
]}

Kennedy, AR ^{[1
]}

O'Hara, CT ^{[1
]}

Mulvey, RE ^{[1
]}

Rowlings, RB ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 04期

关键词：

D O I：

10.1039/b110117j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.

引用

页码：376 / 377

页数：2

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