Resonance Raman characterization of (oxoferryl)tetraphenylporphyrin formed during photodisproportionation of (Fe(TPP))(2)O in a detergent micelle at room temperature

被引：14

作者：

Shantha, PK ^{[1
]}

Verma, AL ^{[1
]}

机构：

[1] NE HILL UNIV,DEPT PHYS,SHILLONG 793022,MEGHALAYA,INDIA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 10期

关键词：

D O I：

10.1021/ic951293d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the formation and characterization of (oxoferryl)tetraphenylporphyrin ((TPP)Fe-IV=O) as a result of photodisproportionation of the mu-oxo dimer, (Fe(TPP))(2)O, obtained on solubilization of Fe(TPP)Cl in an aqueous alkaline TX-100 detergent micelle, under 441.6 nm laser excitation at room temperature and at -50 degrees C. The other photoproduct is identified as a five-coordinated, high-spin (5cHS) ferrous complex.

引用

页码：2723 / 2725

页数：3

共 47 条

[1] FORMATION OF FERRYLTETRAPHENYLPORPHYRIN BY LASER IRRADIATION [J].

BAJDOR, K ;

NAKAMOTO, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (10) :3045-3046

[2]

BELL SEJ, 1991, J CHEM SOC PERK T, V2, P549

[3] RESONANCE RAMAN-SPECTRA AND VIBRATIONAL MODES OF IRON(III) TETRAPHENYLPORPHINE MU-OXO DIMER - EVIDENCE FOR PHENYL INTERACTION AND LACK OF DIMER SPLITTING [J].

BURKE, JM ;

KINCAID, JR ;

SPIRO, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (19) :6077-6083

[4] STRUCTURE-SENSITIVE RESONANCE RAMAN BANDS OF TETRAPHENYL AND PICKET FENCE PORPHYRIN-IRON COMPLEXES, INCLUDING AN OXYHEMOGLOBIN ANALOG [J].

BURKE, JM ;

KINCAID, JR ;

PETERS, S ;

GAGNE, RR ;

COLLMAN, JP ;

SPIRO, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (19) :6083-6088

[5]

CHANG RJ, 1982, INORG CHEM, V21, P2412

[6] TEMPERATURE-DEPENDENT AXIAL LIGATION CHANGES AND PHOTOREDUCTION OF IRON PROTOPORPHYRIN-IX DIMETHYL ESTER CHLORIDE AT LOW-TEMPERATURES MONITORED BY RESONANCE RAMAN TECHNIQUE [J].

CHAUDHURY, NK ;

SAINI, GSS ;

VERMA, AL .

INORGANIC CHEMISTRY, 1995, 34 (01) :346-349

[7] ROLE OF FERRYL (FEO2+) COMPLEXES IN OXYGEN ATOM TRANSFER-REACTIONS - MECHANISM OF IRON(II) PORPHYRIN CATALYZED OXYGENATION OF TRIPHENYLPHOSPHINE [J].

CHIN, DH ;

LAMAR, GN ;

BALCH, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) :5945-5947

[8] ON THE MECHANISM OF AUTOXIDATION OF IRON(II) PORPHYRINS - DETECTION OF A PEROXO-BRIDGED IRON(III) PORPHYRIN DIMER AND THE MECHANISM OF ITS THERMAL-DECOMPOSITION TO THE OXO-BRIDGED IRON(III) PORPHYRIN DIMER [J].

CHIN, DH ;

LAMAR, GN ;

BALCH, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (13) :4344-4350

[9] SYNTHETIC MODELS FOR OXYGEN-BINDING HEMOPROTEINS [J].

COLLMAN, JP .

ACCOUNTS OF CHEMICAL RESEARCH, 1977, 10 (07) :265-272

[10] RESONANCE RAMAN-SPECTROSCOPY REVEALS A1U VS A2U CHARACTER AND PSEUDO-JAHN-TELLER DISTORTION IN RADICAL CATIONS OF NIII, CUII, AND CLFEIII OCTAETHYLPORPHYRINS AND TETRAPHENYLPORPHYRINS [J].

CZERNUSZEWICZ, RS ;

MACOR, KA ;

LI, XY ;

KINCAID, JR ;

SPIRO, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) :3860-3869

← 1 2 3 4 5 →