Resonance Raman characterization of (oxoferryl)tetraphenylporphyrin formed during photodisproportionation of (Fe(TPP))(2)O in a detergent micelle at room temperature

被引：14

作者：

Shantha, PK ^{[1
]}

Verma, AL ^{[1
]}

机构：

[1] NE HILL UNIV,DEPT PHYS,SHILLONG 793022,MEGHALAYA,INDIA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 10期

关键词：

D O I：

10.1021/ic951293d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the formation and characterization of (oxoferryl)tetraphenylporphyrin ((TPP)Fe-IV=O) as a result of photodisproportionation of the mu-oxo dimer, (Fe(TPP))(2)O, obtained on solubilization of Fe(TPP)Cl in an aqueous alkaline TX-100 detergent micelle, under 441.6 nm laser excitation at room temperature and at -50 degrees C. The other photoproduct is identified as a five-coordinated, high-spin (5cHS) ferrous complex.

引用

页码：2723 / 2725

页数：3

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