Self-Assembling Decacyclene Triimides Prepared through a Regioselective Hextuple Friedel-Crafts Carbamylation

被引：87

作者：

Pho, Toan V. ^{[1
]}

Toma, Francesca M. ^{[1
]}

Chabinyc, Michael L. ^{[1
]}

Wudl, Fred ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Dept Mat, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 05期

基金：

美国国家科学基金会;

关键词：

aromatic substitution; fused-ring systems; imides; polycycles; self-assembly; THIN-FILM TRANSISTORS; FIELD-EFFECT TRANSISTORS; LARGE-AREA ELECTRONICS; C-H TRANSFORMATION; SOLAR-CELLS; ORGANIC SEMICONDUCTORS; PHOTOVOLTAIC CELLS; POLYMER; CRYSTALLINE; COMBINATION;

D O I：

10.1002/anie.201207608

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular electronics: A hextuple Friedel-Crafts carbamylation is reported in the synthesis of the electroactive decacyclene triimides (see picture). These triimides self-assemble into different nanostructures through modification of the alkyl substituents and are promising n-type materials for organic semiconducting devices. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1446 / 1451

页数：6

共 54 条

[1] Liquid-crystalline and electron-deficient coronene oligocarboxylic esters and imides by twofold benzogenic Diels-Alder reactions on perylenes [J].