N-heterocyclic carbenes as ligands in high-valent molybdenum and tungsten complexes

被引：57

作者：

Herrmann, WA

Lobmaier, GM

Elison, M

机构：

[1] Anorganisch-chemisches Institut, Tech. Universität München, D-85747 Garching b. München

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 520卷 / 1-2期

关键词：

molybdenum(VI); tungsten(VI); imidazoline-2-ylidene; heterocyclic carbenes;

D O I：

10.1016/0022-328X(96)06296-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxometal complexes of molybdenum and tungsten in high oxidation states form stable adducts with 1,3-dimethylimidazoline-2-ylidene(L) 1. The first 'carbene' complexes of molybdenum(VI) [MoO2Cl(L)(3)]Cl (3a) and tungsten(VI) WO2Cl2(L)(2) (4b) are reported.

引用

页码：231 / 234

页数：4

共 30 条

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