ADDITION-COMPOUNDS OF DICHLORODIOXOMOLYBDENUM(VI) FROM HYDROCHLORIC-ACID SOLUTIONS OF MOLYBDENUM TRIOXIDE - CRYSTAL-STRUCTURE OF DICHLORODIOXODIAQUAMOLYBDENUM(VI) BIS(2,5,8-TRIOXANONANE)

被引：44

作者：

ARNAIZ, FJ ^{[1
]}

AGUADO, R ^{[1
]}

SANZAPARICIO, J ^{[1
]}

MARTINEZRIPOLL, M ^{[1
]}

机构：

[1] CSIC,INST ROCASOLANO,DEPT CRISTALOG,E-28006 MADRID,SPAIN

来源：

POLYHEDRON | 1994年 / 13卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83432-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The behaviour of hydrochloric acid solutions Of MoO3 with some common solvents has been explored. MoO2Cl2(H2O)2 separates from solution stabilized as polyether solvates. The crystal structure of [MoO2Cl2(H2O)2(2,5,8-trioxanonane)2] presents octahedral MoO2Cl2(H2O)2 Units linked to the polyether chains through hydrogen bonds involving the water molecules. The polyether molecules show a cis-cis conformation.

引用

页码：2745 / 2749

页数：5

共 25 条

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