4 COORDINATE BIS(IMIDO) ALKENE COMPLEXES OF MOLYBDENUM(IV) - RELATIVES OF THE ZIRCONOCENE FAMILY

被引：85

作者：

DYER, PW ^{[1
]}

GIBSON, VC ^{[1
]}

HOWARD, JAK ^{[1
]}

WHITTLE, B ^{[1
]}

WILSON, C ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,SCI LABS,SOUTH RD,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 22期

关键词：

D O I：

10.1039/c39920001666

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unusual four coordinate bis(imido) alkene complexes [Mo(NBUt)2(CH2=CHR)(PMe3)] (R = H, Me) have been synthesised via treatment of [Mo(NBUt)2Cl2(dme)] (dme = dimethoxyethane) with two equivalents of RCH2CH2MgCl (R = H, Me) in the presence of PMe3; the molecular structure of the propene derivative is reported.

引用

页码：1666 / 1668

页数：3

共 15 条

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