A new octahedral, liquid-crystalline complex containing a bulky ruthenium fragment

被引：59

作者：

Barral, MC

Jiménez-Aparicio, R

Priego, JL

Royer, EC

Torres, MR

Urbanos, FA

机构：

[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan, E-28040 Madrid, Spain

[2] Univ Complutense Madrid, Fac Ciencias Quim, Ctr Asistencia Invest Rayos X, E-28040 Madrid, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 04期

关键词：

ruthenium complexes; hydride compounds; carboxylate complexes; liquid crystals; mesogenic properties;

D O I：

10.1016/S1387-7003(99)00035-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of RuClH(CO)(PPh3)(3) with HO2CC6H4-p-O2CC6H4-p-O (CH2)(3)CH3 gives the complex RuCl(O2CC6H4-p-O2CC6H4-p-OBu) (CO) (PPh3)(2). The crystal structure shows, in the solid state, molecules of the complex ordered parallel to one another giving layers. This compound has a bulky metallic fragment but however shows a calamitic liquid crystal behavior induced by the carboxylate ligand. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：153 / 155

页数：3

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