Nucleoside adducts of vinylporphyrins and vinylchlorins

被引：18

作者：

Jiang, XQ

Pandey, RK

Smith, KM

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

[2] ROSWELL PK CANC INST,DEPT RADIAT BIOL,PDT CTR,DIV CHEM,BUFFALO,NY 14263

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 13期

关键词：

D O I：

10.1039/p19960001607

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ethene-linked nucleoside derivatives of porphyrins and chlorins have been synthesized by palladium-catalysed coupling between acetylated 5-chloromercuriuridine and various vinylporphyrins and vinylchlorins. The formation of both the trans-(e.g. 22, 24, 29) and gem-(e.g. 23, 30) isomeric products was usually observed in these coupling reactions, and ratios of these isomers were dependent upon the particular substrate employed.

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页码：1607 / 1615

页数：9

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