Synthesis and characterization of polyalkylated Pb(C5Me4R)2 plumbocenes, including the X-ray crystal structure of Pb(C5Me4H)2

被引：9

作者：

Evans, WJ ^{[1
]}

Clark, RD ^{[1
]}

Forrestal, KJ ^{[1
]}

Ziller, JW ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 12期

关键词：

D O I：

10.1021/om990064m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2 equiv of LiC5Me4R (R = H, Pr-i, Bu-n) with PbCl2 affords the Pb(C5Me4R)(2) metal-locenes in good yields. Pb((C5Me4Pr)-Pr-i)2 and Pb((C5Me4Bu)-Bu-n)(2) were isolated as red oils, while Pb(C5Me4H)(2) was isolated as an orange solid whose X-ray crystal structure reveals a bent-metallocene structure which has a 139.7 degrees (ring celitroid)-Pb-(ring centroid) angle.

引用

页码：2401 / 2402

页数：2