Chiral biscavitand propellers: Synthesis, conformations and multiple guest binding

被引：14

作者：

Barrett, ES ^{[1
]}

Irwin, JL ^{[1
]}

Turner, P ^{[1
]}

Sherburn, MS ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 09期

关键词：

D O I：

10.1021/ol025704n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHIC] The synthesis and properties of molecules containing two cavitand bowls, with interbowl linkages comprising one carbon atom at various oxidation levels, are reported. A carbonyl-bridged biscavitand binds three CH2Cl2 molecules in the solid state through a helical conformation. Evidence for the same chiral conformation in the solution phase is presented.

引用

页码：1455 / 1458

页数：4

共 29 条

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