Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

被引：148

作者：

Vodak, DT ^{[1
]}

Braun, ME ^{[1
]}

Kim, J ^{[1
]}

Eddaoudi, M ^{[1
]}

Yaghi, OM ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b108684g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two crystalline metal-organic frameworks formulated as Zn-6(NDC)(5)(OH)(2)(DMT)(2). 4DMF, MOF-48, and Zn-7(m-BDC)(6)(OH)(4)(H2O)(2). 6DMF . 4H(2)O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC = 1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.

引用

页码：2534 / 2535

页数：2

共 17 条

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