Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks

被引：82

作者：

Kawamichi, Takehide ^{[1
]}

Kodama, Tomoki ^{[2
]}

Kawano, Masaki ^{[1
]}

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Toyota Motor Co Ltd, Higashifuji Tech Ctr, Mat Engn Div 3, Shizuoka 4101193, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 42期

基金：

日本科学技术振兴机构;

关键词：

coordination polymer; crystal engineering; host-guest systems; X-ray diffraction; zinc;

D O I：

10.1002/anie.200802545

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) In a crystal, yet as in solution: Bulky reagents are sufficiently mobile in the pores of a porous network complex to react with imbedded substrates in a single-crystal-to-single-crystal fashion. Acylation and ureidation of amines and Schiff-base formation from aldehydes occur efficiently. The pore of the complex thus serves as a crystalline molecular flask, where reaction products are simply determined by X-ray crystallographic analysis. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8030 / 8032

页数：3

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