Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks

被引:82
作者
Kawamichi, Takehide [1 ]
Kodama, Tomoki [2 ]
Kawano, Masaki [1 ]
Fujita, Makoto [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] Toyota Motor Co Ltd, Higashifuji Tech Ctr, Mat Engn Div 3, Shizuoka 4101193, Japan
基金
日本科学技术振兴机构;
关键词
coordination polymer; crystal engineering; host-guest systems; X-ray diffraction; zinc;
D O I
10.1002/anie.200802545
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) In a crystal, yet as in solution: Bulky reagents are sufficiently mobile in the pores of a porous network complex to react with imbedded substrates in a single-crystal-to-single-crystal fashion. Acylation and ureidation of amines and Schiff-base formation from aldehydes occur efficiently. The pore of the complex thus serves as a crystalline molecular flask, where reaction products are simply determined by X-ray crystallographic analysis. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:8030 / 8032
页数:3
相关论文
共 40 条
  • [1] [Anonymous], 2004, Angew. Chem, V116, P2388, DOI DOI 10.1016/j.jechem.2020.01.001
  • [2] Batten S.R., 1998, ANGEW CHEM, V110, P1558, DOI DOI 10.1002/(SICI)1521-3757(19980605)110:11<1558::AID-ANGE1558>3.0.CO
  • [3] 2-7
  • [4] Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
  • [5] 2-Z
  • [6] TOPOCHEMISTRY .1. SURVEY
    COHEN, MD
    SCHMIDT, GMJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN): : 1996 - +
  • [7] Photoinduced linkage isomers of transition-metal nitrosyl compounds and related complexes
    Coppens, P
    Novozhilova, I
    Kovalevsky, A
    [J]. CHEMICAL REVIEWS, 2002, 102 (04) : 861 - 883
  • [8] Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure
    Costa, Jose Sanchez
    Gamez, Patrick
    Black, Cory A.
    Roubeau, Olivier
    Teat, Simon J.
    Reedijk, Jan
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) : 1551 - 1554
  • [9] A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H2O)4- cluster
    Custelcean, R
    Gorbunova, MG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (47) : 16362 - 16363
  • [10] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330