Tetrel-Bonding Interaction: Rediscovered Supramolecular Force?

被引：546

作者：

Bauza, Antonio ^{[1
]}

Mooibroek, Tiddo J. ^{[2
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Palma De Mallorca 07122, Baleares, Spain

[2] Univ Bristol, Sch Chem, Bristol, Avon, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 47期

关键词：

ab initio calculations; group; 14; elements; noncovalent interactions; silicon; supramolecular chemistry; BETA-DONOR BONDS; CRYSTAL-STRUCTURE; HYDROGEN;

D O I：

10.1002/anie.201306501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The w(hole) picture: A tetrel bond is a directional noncovalent interaction between a covalently bonded atom of Group IV and a negative site, for example, the lone pair of a Lewis base or an anion. It involves a region of positive electrostatic potential (σ hole), and energetically, they are comparable to hydrogen bonds and other σ-hole-based interactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12317 / 12321

页数：5

共 21 条

[1]

Ariga Katsuhiko., 2006, Supramolecular Chemistry- Fundamentals and Applications: Advanced Textbook

[2] Defining the hydrogen bond: An account (IUPAC Technical Report) [J].

Arunan, Elangannan ;

Desiraju, Gautam R. ;

Klein, Roger A. ;

Sadlej, Joanna ;

Scheiner, Steve ;

Alkorta, Ibon ;

Clary, David C. ;

Crabtree, Robert H. ;

Dannenberg, Joseph J. ;

Hobza, Pavel ;

Kjaergaard, Henrik G. ;

Legon, Anthony C. ;

Mennucci, Benedetta ;

Nesbitt, David J. .

PURE AND APPLIED CHEMISTRY, 2011, 83 (08) :1619-1636

[3]

Atwood J. L., 2004, ENCYCLOPEDIA OF SUPR

[4]

Bassindale A.R., 2003, Angew. Chem, V115, P3612

[5] Fluoride-ion encapsulation within a silsesquioxane cage [J].

Bassindale, AR ;

Pourny, M ;

Taylor, PG ;

Hursthouse, MB ;

Light, ME .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (30) :3488-3490

[6]

CAULLET P, 1991, EUR J SOL STATE INOR, V28, P345

[7] Amine-promoted disproportionation and redistribution of trichlorosilane: Formation of tetradecachlorocyclohexasilane dianion [J].

Choi, SB ;

Kim, BK ;

Boudjouk, P ;

Grier, DG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8117-8118

[8] Tautomeric equilibrium between penta- and hexacoordinate silicon chelates. A chloride bridge between two pentacoordinate silicons [J].

Kalikhman, I ;

Girshberg, O ;

Lameyer, L ;

Stalke, D ;

Kost, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (20) :4709-4716

[9]

Mitzel N.W., 1997, ANGEW CHEM, V109, P2897, DOI 10.1002/ange.19971092422

[10] beta-donor bonds in SiON units: An inherent structure-determining property leading to (4+4)-coordination in tetrakis-(N,N-dimethylhydroxylamido)silane [J].

Mitzel, NW ;

Blake, AJ ;

Rankin, DWH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (18) :4143-4148

← 1 2 3 →