Fluoride-ion encapsulation within a silsesquioxane cage

被引：146

作者：

Bassindale, AR

Pourny, M

Taylor, PG

Hursthouse, MB

Light, ME

机构：

[1] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England

[2] Univ Southampton, EPSRC Natl Crystallog Serv, Southampton SO17 1BJ, Hants, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 30期

关键词：

anions; cage compounds; fluorides; silicon ligands; silicon;

D O I：

10.1002/anie.200351249

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Taming the caged ion: The X-ray crystal structure of an octaphenyl octasilses-quioxane cage that encapsulates a fluoride ion is presented (see picture). The extent of the Si-F interaction is low, which causes the cage geometry to not change significantly from that of a normal T8 structure. The crystal structure and the NMR data suggest the fluoride ion is essentially naked"."

引用

页码：3488 / 3490

页数：3

共 22 条

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