'Naked fluoride ion' from elemental fluorine

被引：14

作者：

Chambers, RD ^{[1
]}

Gray, WK ^{[1
]}

Sandford, G ^{[1
]}

Vaughan, JFS ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 94卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

naked fluoride ion; elemental fluorine; NMR;

D O I：

10.1016/S0022-1139(99)00010-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetrakis(dimethylamino)ethene 1 reacts with elemental fluorine to give a salt 3, which contains anhydrous fluoride ion as indicated by the F-19 NMR chemical shift. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：213 / 215

页数：3

相关论文

共 11 条

[1] STRUCTURES OF STERICALLY OVERCROWDED AND CHARGE-PERTURBED MOLECULES .12. TETRAKIS(DIMETHYLAMINO)ETHENE - AN EXTREMELY ELECTRON-RICH MOLECULE WITH UNUSUAL STRUCTURE BOTH IN THE CRYSTAL AND IN THE GAS-PHASE
BOCK, H
BORRMANN, H
HAVLAS, Z
OBERHAMMER, H
RUPPERT, K
SIMON, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1991, 30 (12) : 1678 - 1681
[2] REACTIONS INVOLVING FLUORIDE-ION .38. NEW FLUORINATED DIENES BY DEFLUORINATION
BRISCOE, MW
CHAMBERS, RD
MULLINS, SJ
NAKAMURA, T
VAUGHAN, JFS
DRAKESMITH, FG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (21): : 3115 - 3118
[3] SOLVATION OF FLUORIDE IONS
CARMONA, C
EATON, G
SYMONS, MCR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (12) : 873 - 874
[4] Elemental fluorine .2. Direct fluorination of 1,3-dicarbonyl compounds
Chambers, RD
Greenhall, MP
Hutchinson, J
[J]. TETRAHEDRON, 1996, 52 (01) : 1 - 8
[5] Elemental fluorine .1. Synthesis of fluoroaromatic compounds
Chambers, RD
Skinner, CJ
Hutchinson, J
Thomson, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (07): : 605 - 609
[6] Elemental fluorine .3. The preparation of dialkyl fluoromalonates by direct fluorination
Chambers, RD
Hutchinson, J
Thomson, J
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1996, 78 (02) : 165 - 166
[7] REACTION OF THE FLUORIDE ANION WITH ACETONITRILE, CHLOROFORM AND METHYLENE-CHLORIDE
CHRISTE, KO
WILSON, WW
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1990, 47 (01) : 117 - 120
[8] NUCLEAR MAGNETIC-RESONANCE SPECTRUM OF THE FLUORIDE ANION
CHRISTE, KO
WILSON, WW
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1990, 46 (02) : 339 - 342
[9] HIGH-RESOLUTION SOLID-STATE F-19 NMR-SPECTROSCOPY AS A TOOL FOR THE STUDY OF IONIC FLUORIDES
CLARK, JH
GOODMAN, EM
SMITH, DK
BROWN, SJ
MILLER, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) : 657 - 658
[10] IGUMNOV SM, 1986, B CHEM SOC USSR, P1191