A bio-inspired imidazole-functionalised copper cage complex

被引：33

作者：

Bete, Sarah C. ^{[1
]}

Wuertele, Christian ^{[1
]}

Otte, Matthias ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, Tammannstr 4, D-37077 Gottingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 30期

关键词：

AEROBIC OXIDATION; COORDINATION; SYSTEM; HYDROXYLATION; ALCOHOLS; BINDING; MODELS; PEROXO; SITES; ZN;

D O I：

10.1039/c9cc00437h

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

An imidazole-functionalised cage is synthesised that can coordinate to Cu(i). X-ray analysis reveals a T-shaped coordination of copper by the imidazole ligands reminiscent of the coordination geometry found in enzymatic active sites. This cage complex can catalyse the oxidation of benzylic alcohols to benzaldehydes utilizing oxygen as the terminal oxidant.

引用

页码：4427 / 4430

页数：4

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