Iridium(I)-catalysed asymmetric hydrosilylation of ketones using a chiral oxazolylferrocene-phosphine hybrid ligand

被引：73

作者：

Nishibayashi, Y ^{[1
]}

Segawa, K ^{[1
]}

Takada, H ^{[1
]}

Ohe, K ^{[1
]}

Uemura, S ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 07期

关键词：

D O I：

10.1039/cc9960000847

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chiral oxazolylferrocene-phosphine hybrid ligand (DIPOF) is a very effective ligand for Ir-I-catalysed asymmetric hydrosilylation of simple ketones to give the corresponding sec-alcohols (up to 96% ee) after acid hydrolysis.

引用

页码：847 / 848

页数：2

共 9 条

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