Synthesis of poly(vinyl acetate) block copolymers by successive RAFT and ATRP with a bromoxanthate iniferter

被引：79

作者：

Nicolay, Renaud ^{[1
]}

Kwak, Yungwan ^{[1
]}

Matyjaszewski, Krzysztof ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 42期

基金：

美国安德鲁·梅隆基金会;

关键词：

D O I：

10.1039/b810778e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(vinyl acetate)-b-polystyrene, poly(vinyl acetate)-b-poly-(methyl acrylate) and poly(vinyl acetate)-b-poly(methyl methacrylate) block copolymers with low polydispersity (M-w/M-n < 1.25) were prepared by successive reversible addition-fragmentation chain transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) employing a bromoxanthate iniferter (initiator-transfer agent-terminator).

引用

页码：5336 / 5338

页数：3