Tandem reactions catalyzed by lanthanide iodides. Part 2: Tandem iminoaldol-enolisation reactions

被引：9

作者：

Gil, R ^{[1
]}

Eternot, M ^{[1
]}

Guillerez, MG ^{[1
]}

Collin, J ^{[1
]}

机构：

[1] Univ Paris 11, ICMMO, Lab Catalyse Mol, UMR 8075, F-91405 Orsay, France

来源：

TETRAHEDRON | 2004年 / 60卷 / 13期

关键词：

samarium diiodide; catalysis; imines; Mannich reaction; tandem reaction;

D O I：

10.1016/j.tet.2004.01.082

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Samarium diiodide is a catalyst for the reaction of cyclic and acyclic tert-butyldimethylsilyl enoxysilanes with chelating imines. Reaction products are isolated as beta-aminoenoxysilanes instead of beta-aminoketones as previously observed with the corresponding trimethylsilyl enoxysilanes. Several mechanistic pathways are discussed. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：3085 / 3090

页数：6

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