Ruthenium-catalyzed hydroarylations of methylenecyclopropanes: Mild C-H bond functional izations with conservation of cyclopropane rings

被引:93
作者
Kozhushkov, Sergei I. [1 ]
Yufit, Dmitry S. [2 ]
Ackermann, Lutz [1 ]
机构
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
[2] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
D O I
10.1021/ol8011875
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Ring conservation was observed in the first catalytic intermolecular hydroarylation of methylenecyclopropanes via C-H bond functionalization, a remarkable reactivity mode for a transformation proceeding through (cyclopropylcarbinyl)metal intermediates.
引用
收藏
页码:3409 / 3412
页数:4
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