Hydridotris(pyrazolyl)borate ruthenium complexes - properties and applications

被引：92

作者：

Slugovc, C ^{[1
]}

Schmid, R ^{[1
]}

Kirchner, K ^{[1
]}

机构：

[1] Vienna Univ Technol, Inst Inorgan Chem, A-1060 Vienna, Austria

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 185-6卷

关键词：

ruthenium; hydrotris(pyrazolyl)borate; coordination chemistry; catalysis; C-C coupling;

D O I：

10.1016/S0010-8545(98)00251-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review deals with ruthenium complexes of the hydrotris(pyrazolyl)borate (Tp) Ligand and derivatives thereof. The period covered is from 1993 to 1998 (along with a few earlier references) including more than 40 new references, the majority of which have been published in the last 3 years. Among the co-ligands are hydride, dihydrogen, dinitrogen, CO, phosphines and amines. Particular emphasis is on complexes containing metal-carbon single and double bonds. Noteworthy is the synthesis of highly reactive vinylidene complexes and their involvement in stoichiometric C-C coupling reactions with activated alkanes and olefines. Most recent developments include the application of RuTp complexes in catalytic transformations of organic molecules, such as the dimerization and polymerization of acetylenes, and the hydrogenation of ketones. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：109 / 126

页数：18

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