The selective functionalization of saturated hydrocarbons .38. Bis(trimethylsilyl) peroxide: An efficient oxidant for the functionalization of hydrocarbons involving the Fe-II-Fe-IV manifold.

被引：11

作者：

Barton, DHR

Chabot, BM

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON | 1997年 / 53卷 / 02期

关键词：

D O I：

10.1016/S0040-4020(96)00995-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The selective functionalization of alkane was achieved in a good yield. by a simple (FeCl2)-Cl-II salt and bis(trimethylsilyl) peroxide in pyridine. Unlike the Fe-II-H2O2 system, no extra ligand was needed. The presence of a carbon radical from the Fe-II-Fe-IV manifold was proposed to explain the results. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：511 / 520

页数：10

共 26 条

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