Glycerol as an efficient promoting medium for organic reactions

被引：104

作者：

Gu, Yanlong ^{[1
]}

Barrault, Joel ^{[1
]}

Jerome, Francois ^{[1
]}

机构：

[1] Univ Poitiers, CNRS, Catalyse Chim Organ Lab, F-86022 Poitiers, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 13期

关键词：

catalysts; glycerol; green solvents; rate acceleration;

D O I：

10.1002/adsc.200800328

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Whereas the beneficial effect of water on reaction rate is decreased with an increase of the reactant's hydrophobicity, we report here that the use of glycerol as solvent was able to considerably accelerate the reaction rate of an organic reaction even starting from more hydrophobic substrates than those usually used on water. Moreover, the possibility of directly using crude glycerol generated by the biodiesel industry economically and environmentally improves the interest of using glycerol as solvent.

引用

页码：2007 / 2012

页数：6

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