Self-assembling porphyrins and phthalocyanines for photoinduced charge separation and charge transport

被引:167
作者
Imahori, Hiroshi [1 ,2 ,3 ]
Umeyama, Tomokazu [2 ,4 ]
Kurotobi, Kei [1 ]
Takano, Yuta [1 ]
机构
[1] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kyoto Univ, Dept Mol Engn, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
[3] Kyoto Univ, Fukui Inst Fundamental Chem, Sakyo Ku, Kyoto 6068103, Japan
[4] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3320012, Japan
关键词
SENSITIZED SOLAR-CELLS; WALL CARBON NANOTUBES; DISCOTIC LIQUID-CRYSTALS; QUINOXALINE-FUSED PORPHYRINS; ELECTRON-TRANSFER; PHOTOELECTROCHEMICAL PROPERTIES; ELECTROPHORETIC DEPOSITION; MOLECULAR NANOCLUSTERS; FULLERENE DYAD; FILM STRUCTURE;
D O I
10.1039/c2cc30621b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Large pi-conjugated compounds are promising building blocks for organic thin-film electronics such as organic light-emitting diodes, organic field-effect transistors, and organic photovoltaics. Utilization of porphyrins and phthalocyanines for this purpose is highly fascinating because of their excellent electric, photophysical, and electrochemical properties as well as intense self-assembling abilities arising from pi-pi stacking interactions. This paper focuses on fundamental aspects of self-assembled structures that have been obtained from porphyrin and phthalocyanine building blocks and more complex composites for photoinduced charge separation and charge transport toward the potential applications to organic thin-film electronics.
引用
收藏
页码:4032 / 4045
页数:14
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