New fluorination of organic compounds using thermodynamically unstable nickel fluorides

被引：17

作者：

Bartlett, N

Chambers, RD

Roche, AJ

Spinks, RCH

Chacon, L

Whalen, JM

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

[2] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,DIV CHEM SCI,BERKELEY,CA 94720

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 09期

关键词：

D O I：

10.1039/cc9960001049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Replacement of hydrogen by fluorine in a variety of organic compounds is accomplished with high efficiency in liquid hydrogen fluoride (aHF), at or below 20 degrees C, using the thermodynamically unstable fluorides RNiF(3) and NiF4, the latter prepared in situ from K2NiF6 with BF3.

引用

页码：1049 / 1050

页数：2

共 13 条

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[2]

BANKS RE, 1986, FLUORINE 100 YEARS, P267

[3]

CHAMBERS R, IN PRESS

[4] FREE-RADICAL CHEMISTRY .8. ELECTROCHEMICAL FLUORINATION OF PARTLY FLUORINATED ETHERS [J].