Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC6H4SO3]2

被引：83

作者：

Bowes, Katharine F.

Cole, Jacqueline M.

Husheer, Shamus L. G.

Raithby, Paul R.

Savarese, Teresa L.

Sparkes, Hazel A.

Teat, Simon J.

Warren, John E.

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] CCLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

[4] Rutherford Appleton Labs, Diamond Light Source, Didcot OX11 0QX, Oxon, England

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 23期

关键词：

D O I：

10.1039/b604039j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

引用

收藏

页码：2448 / 2450

页数：3

相关论文

共 21 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2] Single-crystal X-ray diffraction studies of photo-induced molecular species [J].

Cole, JM .

CHEMICAL SOCIETY REVIEWS, 2004, 33 (08) :501-513

[3] Crystallography of molecular excited states. Transition-metal nitrosyl complexes and the study of transient species [J].

Coppens, P ;

Fomitchev, DV ;

Carducci, MD ;

Culp, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (06) :865-872

[4] A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction [J].

Coppens, P ;

Gerlits, O ;

Vorontsov, II ;

Kovalevsky, AY ;

Chen, YS ;

Graber, T ;

Gembicky, M ;

Novozhilova, IV .

CHEMICAL COMMUNICATIONS, 2004, (19) :2144-2145

[5] Geometry changes of a Cu(I) phenanthroline complex on photoexcitation in a confining medium by time-resolved x-ray diffraction [J].

Coppens, P ;

Vorontsov, II ;

Graber, T ;

Kovalevsky, AY ;

Chen, YS ;

Wu, G ;

Gembicky, M ;

Novozhilova, IV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :5980-5981

[6] The structure of short-lived excited states of molecular complexes by time-resolved X-ray diffraction [J].

Coppens, P ;

Vorontsov, II ;

Graber, T ;

Gembicky, M ;

Kovalevsky, AY .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2005, 61 :162-172

[7] X-ray diffraction analysis of geometry changes upon excitation: The ground-state and metastable-state structures of K-2[Ru(NO2)(4)(OH)(NO)] [J].

Fomitchev, DV ;

Coppens, P .

INORGANIC CHEMISTRY, 1996, 35 (24) :7021-7026

[8] THE X-RAY CRYSTAL-STRUCTURE OF TRANS-BIS(SULFUR "DIOXIDE)TETRAKIS(TRIPHENYLPHOSPHINE OXIDE)MANGANESE(II) DI-IODIDE, A COMPOUND WHICH UNDERGOES DEMI-REVERSIBLE BINDING OF SULFUR-DIOXIDE - THE 1ST CRYSTALLOGRAPHICALLY CHARACTERIZED EXAMPLE OF O-BONDED SULFUR-DIOXIDE IN A TRANSITION-METAL COMPLEX [J].

GOTT, GA ;

FAWCETT, J ;

MCAULIFFE, CA ;

RUSSELL, DR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (19) :1283-1284

[9] PHOTO-CHEMICAL LINKAGE ISOMERIZATION IN COORDINATED SO2 [J].

JOHNSON, DA ;

DEW, VC .

INORGANIC CHEMISTRY, 1979, 18 (11) :3273-3274

[10] Excited-state structure by time-resolved X-ray diffraction [J].

Kim, CD ;

Pillet, S ;

Wu, G ;

Fullagar, WK ;

Coppens, P .

ACTA CRYSTALLOGRAPHICA SECTION A, 2002, 58 :133-137