Controlled crystallization and granulation of nano-scale β-Ni(OH)2 cathode materials for high power Ni-MH batteries

A novel synthesis of controlled crystallization and granulation was attempted to prepare nano-scale beta-Ni(OH)(2) cathode materials for high power Ni-MH batteries. Nano-scale beta-Ni(OH)(2) and Co(OH)(2) with a diameter of 20nm were prepared by controlled crystallization, mixed by ball milling, and granulated to form about 5 mu m spherical grains by spray drying granulation. Both the addition of nano-scale Co(OH)2 and granulation significantly enhanced electrochemical performance of nano-scale Ni(OH)(2). The XRD and TEM analysis shown that there were a large amount of defects among the crystal lattice of as-prepared nano-scale Ni(OH)(2), and the DTA-TG analysis shown that it had both lower decomposition temperature and higher decomposition reaction rate, indicating less thermal stability, as compared with conventional micro-scale Ni(OH)(2), and indicating that it had higher electrochemical performance. The granulated grains of nano-scale Ni(OH)(2) mixed with nano-scale Co(OH)(2) at Co/Ni = 1/20 presented the highest specific capacity reaching its theoretical value of 289 mAh g(-1) at I C, and also exhibited much improved electrochemical performance at high discharge capacity rate up to 10 C. The granulated grains of nano-scale P-Ni(OH)(2) mixed with nano-scale Co(OH)2 is a promising cathode active material for high power Ni-MH batteries. (c) 2005 Elsevier B.V. All rights reserved.