The effect of crystallinity on the reversible discharge capacity of nickel hydroxide

被引：86

作者：

Jayashree, RS ^{[1
]}

Kamath, PV

Subbanna, GN

机构：

[1] Bangalore Univ, Dept Chem, Cent Coll, Bangalore 560001, Karnataka, India

[2] Indian Inst Sci, Ctr Mat Res, Bangalore 560012, Karnataka, India

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2000年 / 147卷 / 06期

关键词：

D O I：

10.1149/1.1393480

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The higher reversible discharge capacity exhibited by beta(bc) (bc: badly crystalline)-nickel hydroxide (400 mAh g(-1) of Ni; theoretical: 456 mAh g(-1)) compared to that of beta-nickel hydroxide (180 mAh g(-1)) can be attributed to the presence of regions characterized by turbostratic disorder in the former. These regions comprise the alpha-modification of nickel hydroxide existing in an inter-stratified form within the beta(bc) sample. The a-motifs in the beta(bc) are anion-free, but hydrated, by virtue of which beta(bc)-nickel hydroxide exhibits a higher water content (11% by weight) compared to the beta-form (<1%). (C) 2000 The Electrochemical Society. S0013-4651(99)11-003-6. All rights reserved.

引用

页码：2029 / 2032

页数：4

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